Title of article
Catalytic asymmetric C–H activation by methyl thiophen-3-yldiazoacetate applied to the synthesis of (+)-cetiedil
Author/Authors
Davies، نويسنده , , Huw M.L and Walji، نويسنده , , Abbas M and Townsend، نويسنده , , Robert J، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
4981
To page
4983
Abstract
Dirhodium tetraprolinate catalyzed reaction of methyl thiophen-3-yldiazoacetate results in intermolecular allylic C–H activation by means of rhodium carbenoid induced C–H insertion. The reaction with 1,4-cyclohexadiene was applied to the asymmetric synthesis of (+)-cetiedil.
Keywords
C–H insertion , diazo compounds , C–H activation , rhodium carbene
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1652594
Link To Document