Title of article
A new synthetic method for rotaxanes via tandem Claisen rearrangement, diesterification, and aminolysis
Author/Authors
Hiratani، نويسنده , , Kazuhisa and Suga، نويسنده , , Jun-ichi and Nagawa، نويسنده , , Yoshinobu and Houjou، نويسنده , , Hirohiko and Tokuhisa، نويسنده , , Hideo and Numata، نويسنده , , Munenori and Watanabe، نويسنده , , Kunihiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
5747
To page
5750
Abstract
Dimethoxy[2.2]metacyclophane mainly gave a tetrahydropyrene structure and the other [2.n]metacyclophane derivatives (n=3–5) gave aromatic bromides like pseudo-ipso and/or pseudo-ortho dibromides in the reaction with bromine. They also gave benzyl bromides by cyclobutane ring-opening.
Keywords
Rotaxanes , crownophanes , tandem Claisen rearrangement , covalent bond formation , Aminolysis
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1653112
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