Title of article
Synthesis of chiral trans-anti-trans-isomers of dicyclohexano-18-crown-6 via an enzymatic reaction and the solid-state structure of one enantiomer
Author/Authors
Yamato ، نويسنده , , Kazuhiro and Bartsch، نويسنده , , Richard A. and Broker، نويسنده , , Grant A. and Rogers، نويسنده , , Robin D. and Dietz، نويسنده , , Mark L.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
5805
To page
5808
Abstract
Chiral trans-anti-trans-dicyclohexano-18-crown-6 isomers are synthesized via a lipase-catalyzed reaction. The solid-state structure of the (S)-enantiomer is determined and compared with those reported for 18-crown-6 and trans-syn-trans-dicyclohexano-18-crown-6.
Keywords
Stereospecific synthesis , Chiral crown ether , Enzymatic reaction , Solid-state structure
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1653151
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