• Title of article

    Palladium-catalyzed hydrostannylations of highly hindered acetylenes in hexane

  • Author/Authors

    Semmelhack، نويسنده , , M.F. and Hooley، نويسنده , , Richard J.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    3
  • From page
    5737
  • To page
    5739
  • Abstract
    Hexane is particularly favorable as a solvent for hydrostannylation of hindered internal alkynes by minimizing the competing formation of H2 and Bu3SnSnBu3. The optimum conditions involve Pd(OAc)2 and a donor monophosphine (PCy3) in hexane at 23°C.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1653668