Title of article
Two-fold amino acid-based chiral aminophosphine–oxazolines and use in asymmetric allylic alkylation
Author/Authors
Blanc، نويسنده , , Catherine and Hannedouche، نويسنده , , Jérôme and Agbossou-Niedercorn، نويسنده , , Francine، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
5
From page
6469
To page
6473
Abstract
Chiral aminophosphine–oxazoline ligands derived from two different amino acids (tetrahydroisoquinoline carboxylic acid and proline) have been synthesized and examined as chiral auxiliaries in asymmetric allylic alkylation of three substrates. Stereoisomers 1a and 2a are providing the highest enantioselectivities (up to 94% ee) in the allylation of diphenylpropenyl acetate.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654085
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