Title of article
Application of chiral bidentate NMR solvents for assignment of the absolute configuration of alcohols: scope and limitation
Author/Authors
Kobayashi، نويسنده , , Yoshihisa and Hayashi، نويسنده , , Nobuyuki and Kishi، نويسنده , , Yoshito، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
7489
To page
7491
Abstract
The 13C NMR behaviors of several cyclic and biaryl secondary alcohols as well as acyclic tertiary alcohols have been studied in the chiral bidentate NMR solvent BMBA-p-Me (1). An empirical rule has been advanced to correlate the absolute configuration of each type of alcohols with the 13C chemical shift behaviors in (R,R)- and (S,S)-BMBA-p-Me.
Keywords
chiral NMR solvent , NMR database , absolute configuration
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1654856
Link To Document