Title of article
Silenes as novel synthetic reagents: synthesis of diols and lactones from simple alkyldienes
Author/Authors
Berry، نويسنده , , Malcolm B. and Griffiths، نويسنده , , Russell J. and Sanganee، نويسنده , , Mahesh J. and Steel، نويسنده , , Patrick G. and Whelligan، نويسنده , , Daniel K.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
9135
To page
9138
Abstract
Aryl substituted silenes can be generated by a modified Peterson olefination reaction and trapped in situ to afford silacycles with high diastereoselectivity. These silacycles can be elaborated by ‘Fleming–Tamao’ type oxidation to provide access to functionalized diols and lactones.
Keywords
Silene , Diels–Alder cycloaddition , silacycles , Fleming–Tamao oxidation , Diols , Lactones
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1655965
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