Title of article
Selective transformation of ascomycin into 11-epi-ascomycin
Author/Authors
Baumann، نويسنده , , Karl and Bacher، نويسنده , , Markus and Damont، نويسنده , , Annelaure and Steck، نويسنده , , Andrea، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
549
To page
551
Abstract
Within the binding domain, ascomycin features the unusual pattern of a masked tricarbonyl moiety, which potentially allows for high structural diversity via simple isomerisation events. A cascade of diastereoselective rearrangement reactions at the binding domain, allowing the conversion of ascomycin into 11-epi-ascomycin is herein reported.
Keywords
Tricarbonyl , binding domain , Epimerisation , Rearrangement , Ascomycin
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1656528
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