Title of article
Silyl group deprotection by Pd/C/H2. A facile and selective method
Author/Authors
Kim، نويسنده , , Seongjin and Marie Jacobo، نويسنده , , Sheila and Chang، نويسنده , , Chih-Tsung and Bellone، نويسنده , , Sophie and Powell، نويسنده , , William S. and Rokach، نويسنده , , Joshua، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
1973
To page
1976
Abstract
An easy, high yield, RT, short-reaction-time Pd/C hydrogenation of silyl groups is described. This includes TES, TPS, TBS, TBDMS, TIPS, and TBDPS. The relative selectivity of the process has been investigated and we can show, for example, that TES, TPS, TBS, and TBDMS removal can be performed in the presence of TIPS and TBDPS.
Keywords
TES , TPS , TBS , TBDPS , tBDMS , Hydrogenolysis , TIPS
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1657367
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