Title of article
Semi-pinacol strategy for constructing B-ring of pradimicin–benanomicin antibiotics
Author/Authors
Ohmori، نويسنده , , Ken and Kitamura، نويسنده , , Mitsuru and Ishikawa، نويسنده , , Yuji and Kato، نويسنده , , Hirohisa and Oorui، نويسنده , , Mami and Suzuki، نويسنده , , Keisuke، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
4
From page
7023
To page
7026
Abstract
Semi-pinacol cyclization of compound 8, having an acetal and an aldehyde substituent, was achieved by employing SmI2 and BF3·OEt2, leading to the highly stereoselective formation of cyclized product 9. The vicinal diol in 9 is discriminated, so as to allow selective glycosylation for the synthesis of pradimicin–benanomicin antibiotics.
Keywords
pradimicin , Pinacol , Samarium diiodide , benanomicin
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1658218
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