Title of article
4,5-Dehydrooctafluoro[2.2]paracyclophane: facile generation and extraordinary Diels–Alder reactivity
Author/Authors
Battiste، نويسنده , , Merle A. and Duan، نويسنده , , Jian-Xin and Zhai، نويسنده , , Yi-An and Ghiviriga، نويسنده , , Ion and Abboud، نويسنده , , Khalil A. and Roitberg، نويسنده , , Adrian and Shelton، نويسنده , , G.Robert and Dolbier Jr.، نويسنده , , William R.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
7047
To page
7049
Abstract
Dehydroiodination of 4-iodo-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane by treatment with KOtBu in the presence of benzene, naphthalene, anthracene, or t-butylbenzene affords each of the corresponding Diels–Alder cycloadducts of the presumed aryne intermediate in high yield. The products were characterized by their NMR spectra, with one of them also being confirmed by X-ray crystallography. The extraordinary selectivity/reactivity of the aryne intermediate is discussed.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1658240
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