Title of article
Effect of various acids at different concentrations on the pinacol rearrangement
Author/Authors
De Lezaeta، نويسنده , , Monica and Sattar، نويسنده , , Wajiha and Svoronos، نويسنده , , Paris and Karimi، نويسنده , , Sasan and Subramaniam، نويسنده , , Gopal، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
9307
To page
9309
Abstract
The formation of side products in the pinacol–pinacolone rearrangement was studied as a function of concentration and strength of various aqueous acids using 1H NMR spectroscopy. In all cases, pinacolone was the principal product and in most cases, its relative yield decreased with respect to 2,3-dimethyl-1,3-butadiene, when the acid concentration was lowered or the corresponding conjugate base was added.
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1659577
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