Title of article
The Heck reaction in the presence of molecular oxygen
Author/Authors
Hosokawa، نويسنده , , Takahiro and Kamiike، نويسنده , , Taisuke and Murahashi، نويسنده , , Shun-Ichi and Shimada، نويسنده , , Mamoru and Sugafuji، نويسنده , , Toshihiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2002
Pages
3
From page
9323
To page
9325
Abstract
Palladium-catalyzed reaction of CH2C(R)COOMe (R=H or CH2OH) with PhI in the presence of NEt3 under O2 induces the oxidative dealkylation of NEt3, affording either methyl 3-diethylaminopropionate (3) or methyl (Z)-2-benzyl-3-(N,N′-diethylamino)propenate (6), in case of R=H or R=CH2OH, respectively.
Keywords
Oxidation , Oxygen , PALLADIUM , amination , Heck reaction
Journal title
Tetrahedron Letters
Serial Year
2002
Journal title
Tetrahedron Letters
Record number
1659581
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