• Title of article

    The Heck reaction in the presence of molecular oxygen

  • Author/Authors

    Hosokawa، نويسنده , , Takahiro and Kamiike، نويسنده , , Taisuke and Murahashi، نويسنده , , Shun-Ichi and Shimada، نويسنده , , Mamoru and Sugafuji، نويسنده , , Toshihiro، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2002
  • Pages
    3
  • From page
    9323
  • To page
    9325
  • Abstract
    Palladium-catalyzed reaction of CH2C(R)COOMe (R=H or CH2OH) with PhI in the presence of NEt3 under O2 induces the oxidative dealkylation of NEt3, affording either methyl 3-diethylaminopropionate (3) or methyl (Z)-2-benzyl-3-(N,N′-diethylamino)propenate (6), in case of R=H or R=CH2OH, respectively.
  • Keywords
    Oxidation , Oxygen , PALLADIUM , amination , Heck reaction
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2002
  • Journal title
    Tetrahedron Letters
  • Record number

    1659581