Title of article
Barbier-type allylation of iminium ions generated in situ in aqueous medium
Author/Authors
Estevam، نويسنده , , Idلlia H.S. and Bieber، نويسنده , , Lothar W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
667
To page
670
Abstract
Iminium ions, generated in aqueous solution from secondary amines and formaldehyde, undergo a Barbier-type allylation mediated by tin, aluminum and zinc. The reaction is catalyzed by copper and produces tertiary homoallylamines in up to 85% yield.
Keywords
Barbier reaction , allylation , iminium salts , aqueous solvent
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660211
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