Title of article
A new route for the construction of the AB-ring core of Taxol
Author/Authors
Shimada، نويسنده , , Yumi and Nakamura، نويسنده , , Makoto and Suzuka، نويسنده , , Toshimasa and Matsui، نويسنده , , Junji and Tatsumi، نويسنده , , Ryo and Tsutsumi، نويسنده , , Ken and Morimoto، نويسنده , , Tsumoru and Kurosawa، نويسنده , , Hideo and Kakiuchi، نويسنده , , Kiyomi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
1401
To page
1403
Abstract
A new method for the construction of the AB-ring core of Taxol was developed utilizing a new skeletal transformation protocol as a pivotal step. The acid-catalyzed rearrangement of the cyclopentenone–allene photoadduct gave a bridged seven-membered ketone, which was easily transformed, using the intramolecular Suzuki reaction and the oxidative cleavage of the vicinal diol, to the bicyclic diketone.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660619
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