• Title of article

    Stereoselective synthesis of C15C24 and C25C30 fragments of dolabelides

  • Author/Authors

    Desroy، نويسنده , , Nicolas and Le Roux، نويسنده , , Rémi and Phansavath، نويسنده , , Phannarath and Chiummiento، نويسنده , , Lucia and Bonini، نويسنده , , Carlo and Genêt، نويسنده , , Jean-Pierre، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    1763
  • To page
    1766
  • Abstract
    The stereocontrolled synthesis of a C15C24 fragment of dolabelides is reported. The C19 and C21 hydroxyl-bearing stereocenters were installed using ruthenium-mediated asymmetric hydrogenations of cyclic hemiketal 4 and β-keto ester 7. The C25C30 portion of dolabelides was prepared as well by ring opening of chiral epoxy alcohol 12 to set up the C27 stereogenic center.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1660845