Title of article
Stereoselective synthesis of C15C24 and C25C30 fragments of dolabelides
Author/Authors
Desroy، نويسنده , , Nicolas and Le Roux، نويسنده , , Rémi and Phansavath، نويسنده , , Phannarath and Chiummiento، نويسنده , , Lucia and Bonini، نويسنده , , Carlo and Genêt، نويسنده , , Jean-Pierre، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
1763
To page
1766
Abstract
The stereocontrolled synthesis of a C15C24 fragment of dolabelides is reported. The C19 and C21 hydroxyl-bearing stereocenters were installed using ruthenium-mediated asymmetric hydrogenations of cyclic hemiketal 4 and β-keto ester 7. The C25C30 portion of dolabelides was prepared as well by ring opening of chiral epoxy alcohol 12 to set up the C27 stereogenic center.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660845
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