• Title of article

    A new reaction of vicinal sulfonyliminocarboxylates with phosphites

  • Author/Authors

    Onysʹko، نويسنده , , Petro P and Suvalova، نويسنده , , Olena I. and Rassukana، نويسنده , , Yuliya V and Chudakova، نويسنده , , Tetyana I and Sinitsa، نويسنده , , Anatolii D، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    3
  • From page
    1855
  • To page
    1857
  • Abstract
    The reaction of alkyl trifluoro(organylsulfonylimino)propionates with phosphites occurs with NC transfer of the RSO2 group and leads to sulfonyl-substituted trifluoroalanine derivatives. The novel rearrangement is interpreted as cheletropic 1,4-cycloaddition of the phosphite and subsequent 1,2-shift of the sulfonyl group in the intermediate cyclic phosphorane.
  • Keywords
    polyfluoroalkanesulfonylimines , Phosphites , Phosphoranes , Iminophosphoranes , trifluoroalanine derivatives , Rearrangements , oxazaphospholines
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1660898

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1660898