Title of article
Synthesis of fluorinated drimanes. Preparation of 9αF-drimenin
Author/Authors
Abad، نويسنده , , Antonio and Agullَ، نويسنده , , Consuelo and Cuٌat، نويسنده , , Ana C. and Pardo، نويسنده , , David، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
1899
To page
1902
Abstract
A stereoselective approach to the 9α-fluorinated analogue of the natural drimane sesquiterpene drimenin starting from β-ionone is described. β-Ionone is transformed into a bicyclic β-cetoester from which 9αF-drimenin is prepared through stereoselective electrophilic fluorination at the C-9 with N-fluorobenzenesulfonimide followed by Wittig methylenation, allylic bromination, bromine-hydroxyl exchange and γ-lactonization.
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660927
Link To Document