Title of article
Tributylmagnesium ate complex-mediated bromine–magnesium exchange of bromoquinolines: a convenient access to functionalized quinolines
Author/Authors
Dumouchel، نويسنده , , Sylvain and Mongin، نويسنده , , Florence and Trécourt، نويسنده , , Francois and Quéguiner، نويسنده , , Guy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
3
From page
2033
To page
2035
Abstract
2-, 3- and 4-bromoquinolines were converted to the corresponding lithium tri(quinolyl)magnesates at −10°C by treatment with Bu3MgLi in THF or toluene. The resulting organomagnesium derivatives were quenched by various electrophiles to afford functionalized quinolines.
Keywords
Grignard reagents , ate complexes , Exchange reaction , Quinoline
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1660999
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