• Title of article

    Palladium(0)-catalyzed Mizoroki–Heck reaction and Rh(I)-catalyzed asymmetric hydrogenation of polymer-supported dehydroalanine system

  • Author/Authors

    Doi، نويسنده , , Takayuki and Fujimoto، نويسنده , , Nobuaki and Watanabe، نويسنده , , Jun and Takahashi، نويسنده , , Takashi، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2003
  • Pages
    5
  • From page
    2161
  • To page
    2165
  • Abstract
    We have developed a practical route for the synthesis of peptides containing unnatural amino acids. Mizoroki–Heck reaction of polymer-supported dehydroalanine, followed by asymmetric hydrogenation was accomplished using Pd(0) and Rh(I)–DuPHOS catalysts, respectively, leading to 36 dipeptides containing phenylalanine derivatives with high stereocontrol.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2003
  • Journal title
    Tetrahedron Letters
  • Record number

    1661092