Title of article
Mixtures of chiral and achiral monodentate ligands in asymmetric Rh-catalyzed olefin hydrogenation: reversal of enantioselectivity
Author/Authors
Reetz، نويسنده , , Manfred T. and Mehler، نويسنده , , Gerlinde، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
4593
To page
4596
Abstract
The recently described method of combinatorial asymmetric transition metal catalysis based on the use of mixtures of chiral monodentate P-ligands has been extended to include mixtures of chiral and achiral monodentate P-ligands, reversal of enantioselectivity in Rh-catalyzed olefin hydrogenation being possible in appropriate cases.
Keywords
Asymmetric catalysis , Combinatorial chemistry , Hydrogenation , Rhodium , Phosphorus ligands
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1662535
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