Title of article
Samarium(II) iodide-induced tandem reductive coupling-Dieckmann condensation reaction: one-step synthesis of bicyclic oxacyclopentanecarboxylate from bis-α,β-unsaturated esters
Author/Authors
Shinohara، نويسنده , , Ikuo and Okue، نويسنده , , Masayuki and Yamada، نويسنده , , Yasuji and Nagaoka، نويسنده , , Hiroto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2003
Pages
4
From page
4649
To page
4652
Abstract
The tandem cyclization of bis-α,β-unsaturated esters with SmI2-Sm–THF in the presence of catalytic amount of methanol was found to stereoselectively provide bicyclo[4.3.0]nonan-8-ones and bicyclo[3.3.0]octan-3-ones.
Keywords
samarium and compounds , radicals and radical reactions , annulation , cyclopentanones
Journal title
Tetrahedron Letters
Serial Year
2003
Journal title
Tetrahedron Letters
Record number
1662563
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