Title of article
Electrochemical properties and electronic structures of two neutral nickel bis(1,2-dithiolene) complexes
Author/Authors
Sournia-Saquet، نويسنده , , Alix and Bonneval، نويسنده , , Bénédicte Garreau-de and Chane-Ching، نويسنده , , Kathleen I. and Valade، نويسنده , , Lydie، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
7
From page
84
To page
90
Abstract
The synthesis, spectroscopic and electrochemical characterizations of two neutral bisdithiolene nickel complexes are described. Electrochemical reversibility and bandgap have been measured by different techniques. The influence of the nature and length of the alkyl chain, the type of electrode (Pt microdisk for solutions, ITO-coated glass, Pt wire, and CME (cavity microelectrode) for condensed state) and the solvent have been investigated. Optical transmission measurements in the visible–near-IR (VIS–NIR) region allowed the determination of the optical bandgap.
Keywords
Cavity microelectrode , Spectroelectrochemistry , Electrochemical bandgap , Neutral nickel bisdithiolene complex , Optical bandgap
Journal title
Journal of Electroanalytical Chemistry
Serial Year
2008
Journal title
Journal of Electroanalytical Chemistry
Record number
1666882
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