Title of article
Low-potential electrochemical polymerization of carbazole and its alkyl derivatives
Author/Authors
Wei، نويسنده , , Zhenhong and Xu، نويسنده , , Jingkun and Nie، نويسنده , , Guangming and Du، نويسنده , , Yukou and Pu، نويسنده , , Shouzhi، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
8
From page
112
To page
119
Abstract
High quality polymer films can be easily electrodeposited by low-potential anodic oxidation of carbazole and its alkyl derivatives N-octylcarbazole, N-(6-bromohexyl)carbazole, 1,6-bis(carbazolyl)hexane in boron trifluoride diethyl etherate (BFEE) or mixed electrolytes BFEE + CHCl3. As-formed polymer films showed good redox behavior in monomer free BFEE and were characterized by UV–Vis, infrared, fluorescence spectroscopy and thermal analysis. Fluorescence spectral studies both in solution and in solid state revealed that as-formed polymer films were good blue light emitters with strong emissions at about 420 and 440 nm, respectively.
Keywords
electrochemical polymerization , conducting polymers , Boron trifluoride diethyl etherate , Polycarbazole , Fluorescence properties
Journal title
Journal of Electroanalytical Chemistry
Serial Year
2006
Journal title
Journal of Electroanalytical Chemistry
Record number
1672334
Link To Document