Physico-chemical properties of PbO2-anodes doped with Sn4+and complex ions

The influence of tin ions, complex [NiF6]2−, [SnF6]2− ions on physico-chemical properties of lead dioxide electrodeposited from methanesulfonate electrolytes was studied. SEM images reveal a compact structure with round-shaped grains and X-ray diffractogramms demonstrated that incorporation of tin diminishes the size of crystal particles, while the incorporation of [NiF6]2− causes the increasing of average crystal size. It is shown, that at low polarizations region the oxygen overpotential on micromodified PbO2-electrodes increases in the next line PbO2–[NiF6]2− < PbO2–Sn4+ < PbO2 < PbO2–[SnF6]2− and at high potentials the change of dependence occurs.