Title of article
Structure and electrocompression of chloride adlayers on Cu(111)
Author/Authors
Gründer، نويسنده , , Y. and Drünkler، نويسنده , , A. and Golks، نويسنده , , F. and Wijts، نويسنده , , G. and Stettner، نويسنده , , J. and Zegenhagen، نويسنده , , J. and Magnussen، نويسنده , , O.M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
6
From page
1732
To page
1737
Abstract
The specific adsorption of chloride on Cu(111) from acidic aqueous electrolyte (pH 3) was investigated by in-situ surface X-ray diffraction, revealing an incommensurate hexagonal rotated adlayer. The structure and its potential dependence suggest a strong adsorbate–adsorbate interaction as compared to other halide adlayers on (111)-oriented metal electrode surfaces. The orientational epitaxy can be rationalized by the model suggested by Grey and Bohr (Europhys. Lett. 18, 171, 1992), which is based on symmetry considerations.
Keywords
X-Ray scattering , Halide adsorption , Copper , Solid–liquid interface , epitaxy
Journal title
Surface Science
Serial Year
2011
Journal title
Surface Science
Record number
1686178
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