Title of article
Influence of cation size on ionic glass formation and ionic conductivity
Author/Authors
Dillon، نويسنده , , Rensl E.A. and Shriver، نويسنده , , Duward F.، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2000
Pages
7
From page
93
To page
99
Abstract
The salts Na[CF3SO2N(CH2)3OCH3] and K[CF3SO2N(CH2)3OCH3] form amorphous complexes with cryptand and crown ether macrocycles, which exhibit substantial ionic conductivity. The formation of an amorphous phase is thought to be favored by a mismatch between the cavity size of the macrocycle and the diameter of the cation. Complexes were examined by thermal, spectroscopic and conductivity methods to determine the role of the cation and the size mismatch with complexing macrocycles on ionic glass formation.
Keywords
Cryptands , ionic conductivity , Crown Ethers , Polymer electrolytes
Journal title
Solid State Ionics
Serial Year
2000
Journal title
Solid State Ionics
Record number
1706993
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