Title of article
Liquid–liquid equilibria for ternary systems of dimethyl carbonate + C1–C4 alcohols + water at 298.15 K and atmospheric pressure
Author/Authors
Hwang، نويسنده , , In-Chan and Park، نويسنده , , So-Jin and Han، نويسنده , , Kyu-Jin and In، نويسنده , , Se-Jin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
5
From page
499
To page
503
Abstract
The ternary liquid–liquid equilibria (LLE) of the following systems were analytically determined at 298.15 K and atmospheric pressure using stirred and thermo-regulated cells: {dimethyl carbonate (DMC) + methanol + water}, {DMC + ethanol + water}, {DMC + 1-propanol + water}, {DMC + 2-propanol + water}, {DMC + 1-butanol + water} and {DMC + 2-butanol + water}. The experimental ternary LLE data were correlated with the non-random two liquid (NRTL) and UNIversal QUAsiChemical (UNIQUAC) activity coefficient models. In addition, the Bachman–Brown correlation was used to ascertain the reliability of the experimental data for each system.
Keywords
water , Correlation , Liquid–liquid equilibria , Dimethyl carbonate , alcohols
Journal title
Journal of Industrial and Engineering Chemistry
Serial Year
2012
Journal title
Journal of Industrial and Engineering Chemistry
Record number
1709820
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