Nano-TiO2 modified with 2-mercaptobenzimidazole as an efficient adsorbent for removal of Ag(I) from aqueous solutions

Nano-TiO2 was modified with 2-mercaptobenzimidazole via surfactant activation and used as an adsorbent for the removal of Ag(I) under optimum conditions. The adsorbent was characterized using powder X-ray diffraction and FT-IR spectroscopy. The equilibrium data were fitted to the Langmuir, Freundlich and Temkin isotherm models. Langmuir isotherm describes the adsorption data better than Freundlich isotherm and Temkin. Kinetic studies showed that the pseudo second order kinetic model fits the adsorption kinetic processes well. Maximum adsorption capacity for Ag(I) was 128.2 mg g−1 of nano-TiO2. The method was successfully applied to the removal of silver from radiology film processing wastewater samples.