Preparation of ultra-high modulus materials from metallocene based linear polyethylenes

In this communication we report the preparation of new ultrahigh modulus tapes from metallocene-based linear polyethylene (LPE) using tensile drawing. Samples have been prepared with a draw ratio in excess of 50 and a room temperature Youngʹs modulus of 103 GPa. The findings represent a natural extension of the previously reported universal relationship between the modulus and the draw ratio. WAXS measurements suggest that the crystal size in the chain direction is as high as 460 إ while SAXS measurements indicate a long period of about 200 إ. This apparent contradiction is resolved by the inter-crystalline bridge model which correlates the modulus with the degree of crystal continuity determined from the longitudinal crystal thickness and the long period. The increase in modulus is attributed to an increase in crystallinity and crystal continuity along the draw direction without any extended chain crystallisation.