Title of article
α- and β-oxygenated aldehydes derived from Diels–Alder reactions as substrates for hydroxynitrile lyases
Author/Authors
Avi، نويسنده , , Manuela and Steinkellner، نويسنده , , Georg and Keilitz، نويسنده , , Juliane and Hajji، نويسنده , , Chakib and Haag، نويسنده , , Rainer and Gruber، نويسنده , , Karl and Griengl، نويسنده , , Herfried، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
6
From page
268
To page
273
Abstract
3,4-Dihydro-2H-pyran-2-carbaldehyde (1) and 2-methoxycyclohex-3-encarbaldehyde (2) obtained by thermal or chemocatalytic Diels–Alder reactions were converted into the corresponding cyanohydrins by hydroxynitrile lyase catalysis. Modelling investigations give a clear interpretation for the steric course of the biocatalytic cyanohydrin reaction of these α- and β-oxygenated aldehydes.
Keywords
enzyme catalysis , molecular modelling , Biocatalysis , Hydroxynitrile lyases , cyanohydrins
Journal title
Journal of Molecular Catalysis B Enzymatic
Serial Year
2009
Journal title
Journal of Molecular Catalysis B Enzymatic
Record number
1714280
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