Phase morphology and impact toughness of impact polypropylene copolymer

Factors influencing the impact toughness of two impact polypropylene copolymers (IPC) with almost the same ethylene content, molecular weight and molecular weight distribution were studied by temperature gradient extraction fractionation (TGEF), scanning electron microscopy (SEM), nuclear magnetic resonance (NMR) and differential scanning calorimetry (DSC). The results indicate that poor interfacial adhesion between the disperse phase and the continuous matrix, larger dimensions and non-uniform distribution of disperse phases are main reasons for the low impact toughness of IPC B that possesses of a low content of ethylene–propylene segmented copolymer with long crystallizable PE and PP sequences as a compatibilizer between the disperse phase and the matrix.