Dynamic mechanical and dielectric relaxation characteristics of poly(trimethylene terephthalate)

The dynamic mechanical and dielectric relaxation properties of a commercial poly(trimethylene terephthalate) [PTT] have been investigated for both quenched and isothermally melt-crystallized specimen films. The relaxation characteristics of PTT were consistent with those of other low-crystallinity semiflexible polymers, e.g. PET and PEEK. While the sub-glass relaxation was largely unperturbed by the presence of the crystalline phase, both calorimetric and broadband dielectric measurements across the glass transition indicated the existence of a sizeable rigid amorphous phase (RAP) fraction in melt-crystallized PTT owing to the constraining influence of the crystal surfaces over the crystal–amorphous interphase region. A strong increase in measured dielectric relaxation intensity (Δɛ) with temperature above Tg indicated the progressive mobilization of the RAP material, as well as an overall loss of correlation amongst the responding dipoles.