Title of article
The exo-substituted η4-cyclopentadiene CpCo(I) complexes: A new kind of ATRP catalysts and the actual catalyst for the cobaltocene-catalyzed ATRP
Author/Authors
Luo، نويسنده , , Xiongxiong and Zhao، نويسنده , , Xi and Xu، نويسنده , , Shansheng and Wang، نويسنده , , Baiquan، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2009
Pages
6
From page
796
To page
801
Abstract
The exo-substituted η4-cyclopentadiene CpCo(I) complexes were found to be the actual catalyst for the cobaltocene-catalyzed ATRP. Cobaltocene is just a precatalyst, which can be converted to the catalyst by the reaction with halide initiator. As a new kind of ATRP catalyst, the exo-substituted η4-cyclopentadiene CpCo(I) complexes can catalyze the living radical polymerization of MMA, styrene, and the block copolymerization of MMA with styrene.
Keywords
ATRP , Cobalt catalyst , Cobaltocene
Journal title
Polymer
Serial Year
2009
Journal title
Polymer
Record number
1732570
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