Title of article
Magnetic properties of triangulo cobalt–hydride cluster [H3Co3(μ2-CO)3(PMe3)6]
Author/Authors
Bo?a، نويسنده , , Roman and Klein، نويسنده , , Hans-Friedrich and Schmidt، نويسنده , , Andreas and Valko، نويسنده , , Mari?n and Linert، نويسنده , , Wolfgang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
6
From page
243
To page
248
Abstract
Transformation of [HCo(CO)(PMe3)3] in tetrahydrofuran under argon at 90°C yields a solid cobalt–hydrido cluster [H3(Co(CO)(PMe3)2)3]. The magnetic susceptibility down to 3.8 K confirms an antiferromagnetic coupling within the Co3 ring and the Co–H interaction is of the antiferromagnetic nature as well: JCo–Co=−192.4 cm−1, JH–Co=−570.0 cm−1, and gCo=2.402.
Journal title
Chemical Physics Letters
Serial Year
2000
Journal title
Chemical Physics Letters
Record number
1772211
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