Title of article
A new six-pulse two-dimensional electron spin echo envelope modulation (ESEEM) correlation spectroscopy
Author/Authors
Song، نويسنده , , R. and Zhong، نويسنده , , Y.C. and Noble، نويسنده , , C.J. and Pilbrow، نويسنده , , J.R. and Hutton، نويسنده , , D.R.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1995
Pages
5
From page
86
To page
90
Abstract
A new six-pulse two-dimensional electron spin echo envelope modulation (2D ESEEM) method is introduced. It is based on augmenting the five-pulse sequence proposed by Gemperle, Schweiger and Ernst with an additional π pulse. It is shown that the intensity ratio of cross peaks to diagonal peaks is significantly enhanced compared with the four-pulse 2D ESEEM method of Höfer, Grupp, Nebenführ and Mehring. A single crystal of KCl doped with Fe(CN)63− is used to demonstrate this new 2D ESEEM spectroscopy together with an effective phase cycling scheme.
Journal title
Chemical Physics Letters
Serial Year
1995
Journal title
Chemical Physics Letters
Record number
1773497
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