Title of article
Hydrogen-bonding interactions and double proton-transfer reactions at both gates of cyclodextrins
Author/Authors
Garc??a-Ochoa، نويسنده , , I. and D??ez L?pez، نويسنده , , M.-A. and Vi?as، نويسنده , , M.H. and Santos، نويسنده , , L. and Mart??nez Ataz، نويسنده , , E. and S?nchez، نويسنده , , F. and Douhal، نويسنده , , A.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1998
Pages
8
From page
335
To page
342
Abstract
We present the first study of double proton-transfer reactions of a guest, 7-hydroxyquinoline (7HQ), with water at both gates of cyclodextrins. The photoinduced double proton-transfer dynamics in the caging capsule (caged dynamics) is markedly slower than that in pure water (free dynamics). The deprotonation rate of caged 7HQ is found to be 14 times faster than that of caged 2-naphthol.
Journal title
Chemical Physics Letters
Serial Year
1998
Journal title
Chemical Physics Letters
Record number
1775730
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