• Title of article

    Fluorescence quenching of azoalkanes by solvent-assisted radiationless deactivation involving CH bonds

  • Author/Authors

    Nau، نويسنده , , Werner M. and Adam، نويسنده , , Waldemar and Scaiano، نويسنده , , J.C.، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1996
  • Pages
    5
  • From page
    92
  • To page
    96
  • Abstract
    Apparently innocuous solvents such as methylene chloride and chloroform efficiently quench the fluorescence of azoalkane 1 with rate constants of up to 108 M−1 s−1 and deuterium effects of ≈ 3.2. This novel fluorescence quenching mechanism by CH bonds is attributed to radiationless deactivation promoted by covalent hydrogen bonding interactions.
  • Journal title
    Chemical Physics Letters
  • Serial Year
    1996
  • Journal title
    Chemical Physics Letters
  • Record number

    1776606

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1776606