Title of article
Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene
Author/Authors
Sulbaek Andersen، نويسنده , , M.P and Ponomarev، نويسنده , , D.A and Nielsen، نويسنده , , O.J and Hurley، نويسنده , , M.D. and Wallington، نويسنده , , T.J، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
423
To page
426
Abstract
Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20–700 Torr of N2, air, or O2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl+C6H5I)=(3.3±0.7)×10−11 cm3 molecule−1 s−1 to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100%. The title reaction proceeds via a displacement mechanism (probably addition followed by elimination).
Journal title
Chemical Physics Letters
Serial Year
2001
Journal title
Chemical Physics Letters
Record number
1778949
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