Title of article
Spin-lattice relaxation in metal-organic platinum(II) complexes
Author/Authors
Homeier، نويسنده , , H.H.H. and Strasser، نويسنده , , J. and Yersin، نويسنده , , H.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
5
From page
280
To page
284
Abstract
The dynamics of spin–lattice relaxation (SLR) of metal-organic Pt(II) compounds is studied. Often such systems are characterized by pronounced zero-field splittings of the lowest-lying triplets. Previous expressions for the Orbach SLR process do not allow proper treatment of such splitting patterns. We discuss the behavior of a modified Orbach expression for a model system. Further, we present results of a fit of the temperature dependence of the SLR rate for Pt(2-thpy)2 based on the modified expression.
Journal title
Chemical Physics Letters
Serial Year
2000
Journal title
Chemical Physics Letters
Record number
1780762
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