Title of article
The Cl to NCl branching ratio in 248-nm photolysis of chlorine azide
Author/Authors
Wodtke، نويسنده , , Alec M. and Hansen، نويسنده , , Nils and Robinson، نويسنده , , Jason C. and Sveum، نويسنده , , Niels E. and Goncher، نويسنده , , Scott J. and Neumark، نويسنده , , Daniel M.، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
334
To page
337
Abstract
The primary reaction products from 248-nm chlorine azide photolysis are identified in a collision-free experiment. In contrast to all previous reports, the radical channel producing Cl + N3 (95 ± 3%) is seen to dominate the photochemistry. The molecular channel producing NCl + N2 (5 ± 3%) was also observed.
Journal title
Chemical Physics Letters
Serial Year
2004
Journal title
Chemical Physics Letters
Record number
1784820
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