Title of article
Tris(pentafluorophenyl)silyl enol ethers: synthesis and aldol reactions
Author/Authors
Dilman، نويسنده , , Alexander D. and Belyakov، نويسنده , , Pavel A and Korlyukov، نويسنده , , Alexander A and Tartakovsky، نويسنده , , Vladimir A، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
3741
To page
3744
Abstract
Silyl enol ethers bearing three pentafluorophenyl groups at the silicon atom are described. These compounds undergo uncatalyzed aldol reactions with aliphatic, α,β-unsaturated, and aromatic aldehydes. The observed reactivity is analyzed in terms of the Lewis acidity of the silyl fragment.
Keywords
Silyl enol ethers , aldol reaction , Silicon Lewis acidity
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1841523
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