Title of article
Rhodium catalysed hydroformylation of unsaturated esters
Author/Authors
Clarke، نويسنده , , Matthew L.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
4043
To page
4045
Abstract
Rhodium catalysed hydroformylation of unsaturated esters has been studied. A pronounced temperature dependence was observed on the regioselectivity and catalytic activity for these reactions, and under the appropriate conditions, it is possible to obtain preferentially either linear or quaternary products. A quaternary selective hydroformylation of methyl atropate to give 1,3-aldehydic esters has also been developed.
Keywords
hydroformylation , Alkoxycarbonylation , Regioselective C–C bond formation , Phosphite , Rhodium , Quaternary carbons
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1841649
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