Title of article
Stereoselective synthesis of 3-glycosyl-5-methoxycarbonyl-isoxazolidines from d-galactose and d-glucose
Author/Authors
Borrachero، نويسنده , , Pastora and Cabrera-Escribano، نويسنده , , Francisca and Gَmez-Guillén، نويسنده , , Manuel and Torres، نويسنده , , Ma Isabel، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
4835
To page
4839
Abstract
Regio- and stereoselective cycloaddition of methyl acrylate to C-glycosyl nitrones derived from d-galactose and d-glucose, giving 5-methoxycarbonyl-3-(pentoglycos-5-yl or pentitol-1-yl)isoxazolidines, is reported. Transformation of one of them into a 4-hydroxy-2-(pentoglycos-5-yl)pyrrolidine derivative, potentially useful in a route to polyhydroxy-perhydroazaazulenes, was achieved.
Keywords
C-Glycosyl nitrones , Methyl acrylate , 3-Glycosyl-5-methoxycarbonyl-isoxazolidines , 6-Amino-6 , Isoxazolidine-ring cleavage , 7-dideoxy-nonopyranosurono-9 , 6-lactams , Polyhydroxy-perhydroazaazulene precursors , stereoselective synthesis
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842120
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