Title of article
On the 6-exo-trig ring closure of substituted 5-hexen-1-oxyl radicals
Author/Authors
Hartung، نويسنده , , Jens and Gottwald، نويسنده , , Thomas، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
5619
To page
5621
Abstract
Substituted 5-hexen-1-oxyl radicals have been generated from N-(5-hexen-1-oxy)-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thiones under tin-free conditions and have been successfully applied as reactive intermediates in a mechanistic study on the formation of bromomethyl-substituted tetrahydropyrans via 6-exo-trig selective cyclizations.
Keywords
tetrahydropyran , Alkoxyl radical , cyclization , Thiazolethione , Bromine atom transfer
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1842528
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