Title of article
Ru3(CO)12-catalyzed intramolecular allylic transfer reaction of tethered carbonyl group and allylic acetate moiety
Author/Authors
Yu، نويسنده , , Chan-Mo and Lee، نويسنده , , Sungwon and Hong، نويسنده , , Young-Taek and Yoon، نويسنده , , Seok-Keun، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
5
From page
6557
To page
6561
Abstract
A ruthenium catalyzed intramolecular allylic transfer reaction of allylic acetates containing aldehydes or ketones to form cis-homoallylic cyclopentanols and cyclohexanols as a major component is described. The use of Ru3(CO)12 (1 mol %) to promote reaction results in a convenient procedure for intramolecular allylation of carbonyl functionalities.
Keywords
Ruthenium , allylation , carbonyl , cyclization , Catalyst
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843065
Link To Document