Title of article
Alcohols oxidation with hydrogen peroxide promoted by TPAP-doped ormosils
Author/Authors
Campestrini، نويسنده , , Sandro and Carraro، نويسنده , , Massimo and Ciriminna، نويسنده , , Rosaria and Pagliaro، نويسنده , , Mario and Tonellato، نويسنده , , Umberto، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
7283
To page
7286
Abstract
Organically modified silica gels doped with TPAP (tetra-n-propylammonium perruthenate) are effective catalysts for the oxidation of alcohols by hydrogen peroxide at room temperature, provided that the oxidant H2O2 solution is added slowly. The effect of the surface catalyst polarity is the opposite of that found in aerobic alcohols oxidation and is consistent with the polar nature of the primary oxidant.
Keywords
Hydrogen peroxide , Sol–gel , Oxidation , Peroxides
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843355
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