Title of article
Twofold Brook rearrangement-mediated tandem reactions of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with a cyanide ion
Author/Authors
Tanaka، نويسنده , , Koudai and Takeda، نويسنده , , Kei، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
7859
To page
7861
Abstract
Reaction of δ-silyl-γ,δ-epoxy-α,β-unsaturated acylsilanes with KCN in the presence of chloro or cyanoformates gives highly functionalized dienol silyl ether derivatives via a twofold Brook rearrangement-induced tandem sequence.
Keywords
Tandem reaction , Brook rearrangement , Acylsilanes , Epoxysilanes
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843569
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