Title of article
A mechanistic study of the Hiyama–Nozaki allylation: evidence for radical intermediates
Author/Authors
Mulzer، نويسنده , , Johann and Strecker، نويسنده , , Achim R. and Kattner، نويسنده , , Lars، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
4
From page
8867
To page
8870
Abstract
In course of chromium(II) mediated additions of relatively complex allylic bromides to aldehydes (Hiyama–Nozaki allylation) radical intermediates have been observed. From these findings a new mechanism of the allylation is derived.
Keywords
Organochromium compounds , Stereoselective allylation of aldehydes , Homoallylic alcohols , Allylic radicals , SET mechanism
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1843988
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