Title of article
Addition of secondary phosphines to a vinyl ether of diacetone-d-glucose: a new approach to optically active phosphines and their derivatives
Author/Authors
Trofimov، نويسنده , , Boris A. and Sukhov، نويسنده , , Boris G. and Malysheva، نويسنده , , Svetlana F. and Belogorlova، نويسنده , , Natal’ya A. and Tantsirev، نويسنده , , Anatolii P. and Parshina، نويسنده , , Lidiya N. and Oparina، نويسنده , , Ludmila A. and Tunik، نويسنده , , Sergey P. and Gusarova، نويسنده , , Nina K.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2004
Pages
3
From page
9143
To page
9145
Abstract
Secondary phosphines react readily with a vinyl ether of diacetone-d-glucose under radical initiation conditions to give, in high yield, anti-Markovnikov adducts, diorganyl{2-[3-O-(1,2:5,6-di-O-isopropylidene)-d-glucofuranosyloxy]ethyl}phosphines, which oxidize almost quantitatively upon reacting with air oxygen or elemental sulfur to form the corresponding optically active phosphine oxides or sulfides.
Keywords
secondary phosphines , Addition , Phosphine oxides and sulfides , Radical initiation , Optically active tertiary phosphines , Vinyl ether of diacetone-d-glucose
Journal title
Tetrahedron Letters
Serial Year
2004
Journal title
Tetrahedron Letters
Record number
1844104
Link To Document